Sunday, January 7, 2024

New applications of wurtzite boron nitride

Wurtzite boron nitride demonstrates  excellent  heat resistance properties, which is well known. But the  main advantage of this material are the highest (among similar heat resistant materials)  stabilities of coating layer and thermal characteristics. This makes wurtzite boron nitride the most appropriate material for coating of melting molds,  3D printers parts  and more. 
Below is an interesting example of heat resistance properties of 100% cotton, impregnated with wurtzite boron nitride paste. Apparently impregnated cotton remains solid for a much longer time, than  pure fabric.


Similar experiment for graphite electrode from National, USA., dimensions 12'x0.8'. The electrode was coated with boron nitride paste and left in oven under temperature of  1832 °F for 8 hours. Oval shows area, which was placed in furnace.  As you see, protected area is also burnt, but much less than the rest of the electrode. 




Tuesday, January 25, 2022

Is wurtzite boron nitride harder than diamond?


 Wurtzite-like, wurtzite boron nitride has recently announced as a material harder than diamond. Such "recentness" is explained by the fact that it is relatively rare in nature, and these comparisons have practically not been made earlier.


Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the following crystal structures:

- BNw (wurtzite structure),
- BNcub (cubic BN), softer than diamond, but its thermal and chemical resistance is higher, used as an abrasive;
- BNhex (hexagonal BN), the most stable and mild among the BN polymorphs, is used as a lubricant and additive in cosmetic products;
- rhombohedral.

   The BNw structure is metastable under any conditions. BNw (wurtzite structure, also known as g-BN) was first synthesized in 1963. As a rule, BN crystals with the symmetry of wurtzite (wurtzite boron nitride powder) are very small (fractions of a micron), highly defective, and contain other phases. In other words, it is practically impossible to measure the strength of these crystals and compare them with diamond: this material is rare in nature, and, according to my data, it has not yet been possible to synthesize a crystal suitable for measuring hardness.

   At the same time, another material related to wurtzite boron nitride, cubic boron nitride, is the second hardest material after diamond, with a fracture force of about 50 GPa; despite the fact that for diamond it is 70–150 GPa.
    However, wurtzite boron nitride and cubic boron nitride have the same wavelength and elastic moduli, which suggests that they can exhibit the same hardness as well. In fact, this "opportunity" is of no value, since it is impossible to apply it in practice due to the size of the wurtzite boron nitride crystal. In other words, it is impossible to make an abrasive wheel or paste suitable for anything other than fine polishing, the breadth of which, although significant (eg in optics), is rather limited compared to sharpening and grinding.

   However, wurtzite-like boron nitride is a promising wide-gap group III-V material for modern electronic devices because it has many properties superior to gallium nitride (GaN) and aluminum nitride (AlN), such as higher thermal conductivity and greater spontaneous polarization.

Thursday, March 18, 2021

Selection of knife sharpening stone

There 3 major factors which must be considered, selecting knife sharpening stone.
 - Abrasive: diamond, cubic boron nitride, etc. 
- Bond: electroplated, metal, resin, ceramic. etc. 
- Grain size. 

 Abrasive selection is, by far, the most difficult, because there is a plenty of brands and materials, offered for sharpening. I am not going to recommend smth specific, or review all of them in detail. Instead I will mention industry practices and science research about the most appropriate materials for grinding, sharpening, and polishing. a. 

As the hardest material, diamond should be regarded as the best material for grinding, and it is widely used nowadays, especially in power grinding of carbide or ceramics. However, the major concern of professional sharpeners about diamond is hardness too, because diamond stones may leave scratches, even if grain size is appropriate. 
 This issue especially relates to cheap oriental stones, whose diamond crystals also often drop out of the bond, instead of “self-sharpen”, as it takes place with more expensive “resin bond” diamonds, made on smaller presses with special synthesis profiles. 
In addition, diamond has relatively low thermal stability, and this makes negative impact, especially on powered processing of ferrous materials. 
 Anyway, diamond sharpening stones by reputable manufacturers should be your choice in hand powered rough grinding, sharpening, and grinding. 
 Cheap diamond sharpening stones (e.g. price below 50USD per stone 150mm x 25 mm) will work too, but tool life will be lower (because of lower grain concentrations) and surface roughness in many cases will disappoint professional sharpener (because of low quality powder screening/water sedimentation). Definitely it is not recommended to use cheap diamond sharpening stones for fine grinding and polishing, simply because low price would not pay off considering efforts to reach desired surface quality.

 b. Cubic boron nitride, the second hardest material after diamond, is regarded as the most suitable for processing of steels. You may find a lot of information about it in Internet, and this article is not a place to prove scientifically proven facts again.
CBN is softer, sharpening with CBN stone is more delicate, but claimed as less productive than with diamond. You may encounter reviews like: “stone A sharpens faster than B, so A is better.” 
 It makes sense in the following cases:
- For products with identical technical parameters (concentration, bond, grain size), so you can make conclusion about level of product quality; 
-For similarly priced products, so you can make a conclusion about advantages of certain abrasive, bond, grain screening. 

However, in most reviews people just take stones, without mentioning their specifications. So, you may find conclusion like: “this reputable manufacturer made another breakout with this electroplated stone…” Firstly, electroplated may be blank only, not stone, and secondly in some operations, this blank is left far behind even by the cheapest manufacturers. Just do not compare apple and oranges. 

 Actually claims that diamond stones are more productive than CBN stone, are false for delicate operations, if you consider possible efforts to polish scratches appeared on previous stages. Apparently in your sharpening set should be both diamond and CBN stones, depending on required productivity and roughness requirements. 

 c. Other  abrasives Plenty of them. Their hardness is lower, their abrasive ability is lower, their sharpening productivity is lower than those of diamond and CBN. They are cheaper. There are no other features, worth mentioning, except the fact that many of them are traditional. Traditions and habits may be more important, than industry practices. 

 Bond is material with holds abrasive. While diamond and CBN powders in most cases are outsourced (purchased from manufacturer of superabrasives, most of which are located in China), bond is where innovations of sharpening stone manufacturer go in. 

 Although there are 3 major well known bonds, manufacturers have “secret ingredients” to differentiate from competitors. 
Resin bond has relatively low hardness and thermal stability. Resin bond is recommended for fine and finishing operations and does not require cooling. Resin bond stones usually require support (metal blank). 

- Metal bond is harder and has high thermal stability. Metal bond is recommended for harder working conditions, with lower tolerances, and often requires cooling. Metal bond stones are often solid blocks without support (blank). 

- Electroplated bond is a single layer of powder in nickel alloy; in rare cases there may be 2 or even 3 layers of diamond or CBN. It is used for cutting tools, dies, points. 

 Electroplated sharpening blanks are cheaper in production and should be the cheapest on the counter. Metal bond sharpening stones are the most expensive in production, the finer grain size, the more difficult it is to distribute grains through the volume of the copper-nickel (or whatever) alloy. Stones with fine grain sizes (below 3 microns, applies also to resin bond stones) either require preparation on cast iron plates, or they will be self-polished after sharpening of 30-50 knives.
There is no question about bond selection for delicate operations, such as fine or glass polishing: of course our choice is resin bond with grains from 0.1 to 3 microns. 
 But for other operations you will need to compare costs of tools: 
- Possession: price of metal bond sharpening stone is higher, 
- Operation: tools life and productivity of metal bond sharpening stone are higher, but it may produce lower tolerances, comparing to resin bond stone with identical grain size.

 Grain size is what defines roughness of processing surface. Grit size notations vary depending on standard. Micron (Ukraine) standard denotes grit size in microns: "the coarsest/the finest sizes" grains in powder's sample, e.g. 160/125. 
Oppositely, US standard ANSI B 74 (notations are known also as GRIT, MESH) denotes grit sizes in meshes per inch, consequently the less meshes are in inch, the coarser is the grit size, e.g. 160/125 micron = 100/120 
 Anyway grain size selection question is mainly not about which grain size to select, but what grain size set you need. 
 As a rule of thumb this may be full set, offered by manufacturer, but at the same time, set of 20+ grain sizes is also costly. In industry grain size is defined by actual and required roughness, but professional sharpeners apply own experience and habits. 
For example, for you, practical choice may be set of sharpening stones 250/200, 125/100, 60/40, 28/20, 1/0 microns. The coarsest grain is defined by actual roughness of most steel knife’s blanks, the finest… some my clients require even grain size 0.1/0 microns, applied for polishing of space mirrors. 

 Another important parameter of sharpening stone is grit concentration. Cost of abrasive (diamond, cubic boron nitride (CBN)) is a significant part (e.g. 40 cents per carat for 20 cts stone) of a cost of a tool. The higher concentration (weight by volume) of diamond in bond, the higher productivity and longer stone's life. 
 Cheap diamond or CBN stones are cheaper not only because manufacturer decided to lower amount of powder in a stone, thus decrease selling price, but also because he is not able to distribute required amount of a powder in a bond. 
 Moreover, there are only few manufacturers, capable to produce stones with grain sizes below 0.5 micron, so cheap sharpening stones with such grain sizes as 0.1/0 micron must not exist at all. 

 I recommend concentration 100%, but in long term, concentration 200% ,(more expensive approx. by 50%) is good choice too. Lower or unknown concentrations are just waste of time and money. 

New applications of wurtzite boron nitride

Wurtzite boron nitride demonstrates  excellent  heat resistance properties, which is well known. But the  main advantage of this material ar...